High‐Performance Non‐Fullerene Organic Solar Cells Based on a Selenium‐Containing Polymer Donor and a Twisted Perylene Bisimide Acceptor
نویسندگان
چکیده
A novel polymer donor (PBDTS-Se) is designed to match with a non-fullerene acceptor (SdiPBI-S). The corresponding solar cells show a high efficiency of 8.22%, which result from synergetic improvements of light harvesting, charge carrier transport and collection, and morphology. The results indicate that rational design of novel donor materials is important for non-fullerene organic solar cells.
منابع مشابه
An Electron Acceptor with Porphyrin and Perylene Bisimides for Efficient Non-Fullerene Solar Cells.
A star-shaped electron acceptor based on porphyrin as a core and perylene bisimide as end groups was constructed for application in non-fullerene organic solar cells. The new conjugated molecule exhibits aligned energy levels, good electron mobility, and complementary absorption with a donor polymer. These advantages facilitate a high power conversion efficiency of 7.4 % in non-fullerene solar ...
متن کاملSynthesis of thienoselenadiazole-containing conjugated copolymers and their application in polymer solar cells
INTRODUCTION In recent years, polymer solar cells (PSCs) have attracted great attention due to the energy crisis all over the world. Compared with inorganic solar cells, PSCs have many advantages, such as light weight, solution processability, mechanical flexibility and low cost.1 The stateof-the-art of PSCs are based on a fullerene-derivative acceptor, such as [6,6]-phenyl-C61-butyric acid met...
متن کاملDonor-Acceptor Block Copolymers: Synthesis and Solar Cell Applications
Fullerene derivatives have been widely used for conventional acceptor materials in organic photovoltaics (OPVs) because of their high electron mobility. However, there are also considerable drawbacks for use in OPVs, such as negligible light absorption in the visible-near-IR regions, less compatibility with donor polymeric materials and high cost for synthesis and purification. Therefore, the i...
متن کاملFluorescence quenching in an organic donor-acceptor dyad: a first principles study.
Perylene bisimide and triphenyl diamine are prototypical organic dyes frequently used in organic solar cells and light emitting devices. Recent Forster-resonant-energy-transfer experiments on a bridged organic dyad consisting of triphenyl diamine as an energy-donor and perylene bisimide as an energy-acceptor revealed a strong fluorescence quenching on the perylene bisimide. This quenching is ab...
متن کاملDonor polymer design enables efficient non-fullerene organic solar cells
To achieve efficient organic solar cells, the design of suitable donor-acceptor couples is crucially important. State-of-the-art donor polymers used in fullerene cells may not perform well when they are combined with non-fullerene acceptors, thus new donor polymers need to be developed. Here we report non-fullerene organic solar cells with efficiencies up to 10.9%, enabled by a novel donor poly...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 3 شماره
صفحات -
تاریخ انتشار 2016